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MechanicalThermodynamicseasyFE ExamCoursework

Heat Added to a Rigid Tank

A rigid, sealed tank contains m=2.0 kgm = 2.0\ \text{kg} of air. The air is heated from 300 K300\ \text{K} to 500 K500\ \text{K}.

For air, cv=0.718 kJ/kg⋅Kc_v = 0.718\ \text{kJ/kg·K}.

Find the heat added to the air.

Given
m2 kgMass of air
T1300 KInitial temperature
T2500 KFinal temperature
cv0.718 kJ/kg*KSpecific heat at constant volume
Hint 1

Start from the first law for a closed system: Q − W = ΔU.

Hint 2

What does 'rigid' tell you about the work term?

Hint 3

With W = 0, Q = ΔU = mc_vΔT. Note it is c_v, not c_p.

Worked solution — try the problem first

First law for a closed system:

QW=ΔUQ - W = \Delta U

The tank is rigid, so the volume cannot change and no boundary work is done:

W=PdV=0W = \int P\,dV = 0

Therefore Q=ΔUQ = \Delta U.

Internal energy change for an ideal gas with constant specific heat uses cvc_v — the constant-volume specific heat — regardless of the process. Here the process happens to be constant volume too, but that is not why cvc_v appears:

ΔU=mcv(T2T1)=2.0×0.718×(500300)\Delta U = m c_v (T_2 - T_1) = 2.0 \times 0.718 \times (500 - 300)

=2.0×0.718×200=287.2 kJ= 2.0 \times 0.718 \times 200 = 287.2\ \text{kJ}

Q=287.2 kJ\boxed{Q = 287.2\ \text{kJ}}

Concepts:First law of thermodynamicsClosed systemsSpecific heats

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