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ChemicalThermodynamicseasyFE ExamCoursework

Density of an Ideal Gas

Carbon dioxide (M=44 g/molM = 44\ \text{g/mol}) is at 200 kPa200\ \text{kPa} and 300 K300\ \text{K}.

Take R=8.314 J/mol⋅KR = 8.314\ \text{J/mol·K} and assume ideal gas behaviour.

Find the density.

Given
P200 kPaPressure
T300 KTemperature
M44 g/molMolar mass
Hint 1

Start from PV = nRT and substitute n = m/M to get a density.

Hint 2

ρ = PM/(RT).

Hint 3

Convert pressure to Pa and molar mass to kg/mol before substituting.

Worked solution — try the problem first

From PV=nRTPV = nRT with n=m/Mn = m/M:

ρ=PMRT\rho = \frac{PM}{RT}

Convert to base SI. Both conversions matter:

P=200 kPa=2.00×105 Pa,M=44 g/mol=0.044 kg/molP = 200\ \text{kPa} = 2.00\times10^{5}\ \text{Pa}, \qquad M = 44\ \text{g/mol} = 0.044\ \text{kg/mol}

ρ=(2.00×105)(0.044)(8.314)(300)=88002494.2=3.528 kg/m3\rho = \frac{(2.00\times10^{5})(0.044)}{(8.314)(300)} = \frac{8800}{2494.2} = 3.528\ \text{kg/m}^3

ρ=3.53 kg/m3\boxed{\rho = 3.53\ \text{kg/m}^3}

Sanity check. Air at ambient conditions is about 1.2 kg/m³. CO₂ is 1.5× heavier per mole than air, and this gas is at twice atmospheric pressure, so roughly 1.2×1.5×2=3.61.2 \times 1.5 \times 2 = 3.6 kg/m³ — consistent.

Concepts:Ideal gas lawDensityUnit conversion

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